Cathodic deposition of MOF films: mechanism and applications

Metal-organic framework (MOF) thin films could be used for ion/molecular sieving, sensing, catalysis, and energy storage, but thus far no large-scale applications are known. One of the reasons is the lack of convenient and controllable fabrication methods. This work reviews the cathodic deposition of MOF films, which has advantages (e.g., simple operations, mild conditions, and controllable MOF film thickness/morphology) over other reported techniques. Accordingly, we discuss the mechanism of the cathodic deposition of MOF films which consists of the electrochemically triggered deprotonation of organic linkers and the formation of inorganic building blocks. Thereafter, the main applications of cathodically deposited MOF films are introduced with the aim of showing this technique's wide-ranging applications. Finally, we give the remaining issues and outlooks of the cathodic deposition of MOF films to drive its future development.