Non-orientable order and non-commutative response in frustrated metamaterials

From atomic crystals to animal flocks, the emergence of order in nature is captured by the concept of spontaneous symmetry breaking^1-4. However, this cornerstone of physics is challenged when broken symmetry phases are frustrated by geometrical constraints. Such frustration dictates the behaviour of systems as diverse as spin ices^5-8, confined colloidal suspensions⁹ and crumpled paper sheets¹⁰. These systems typically exhibit strongly degenerated and heterogeneous ground states and hence escape the Ginzburg-Landau paradigm of phase ordering. Here, combining experiments, simulations and theory we uncover an unanticipated form of topological order in globally frustrated matter: non-orientable order. We demonstrate this concept by designing globally frustrated metamaterials that spontaneously break a discrete [Formula: see text] symmetry. We observe that their equilibria are necessarily heteregeneous and extensively degenerated. We explain our observations by generalizing the theory of elasticity to non-orientable order-parameter bundles. We show that non-orientable equilibria are extensively degenerated due to the arbitrary location of topologically protected nodes and lines where the order parameter must vanish. We further show that non-orientable order applies more broadly to objects that are non-orientable themselves, such as buckled Möbius strips and Klein bottles. Finally, by applying time-dependent local perturbations to metamaterials with non-orientable order, we engineer topologically protected mechanical memories^11-19, achieve non-commutative responses and show that they carry an imprint of the braiding of the loads' trajectories. Beyond mechanics, we envision non-orientability as a robust design principle for metamaterials that can effectively store information across scales, in fields as diverse as colloidal science⁸, photonics²⁰, magnetism⁷ and atomic physics²¹.