Related Experiment Video
Updated: Jul 26, 2025

08:12
Low Pressure Vapor-assisted Solution Process for Tunable Band Gap Pinhole-free Methylammonium Lead Halide Perovskite Films
Published on: September 8, 2017
9.6K
A two-dimensional lead-free hybrid perovskite semiconductor with reduced melting temperature
Akash Singh1,2, Ethan Crace1, Yi Xie1,2
1Department of Mechanical Engineering and Materials Science, Duke University, Durham, North Carolina 27708, USA. david.mitzi@duke.edu.
Abstract:
1-Methylhexylammonium tin iodide yields the lowest reported melting temperature (Tm = 142 °C) to date among lead-free hybrid perovskite semiconductors. Molecular branching near the organic ammonium group coupled with tuning of metal/halogen character suppresses Tm and facilitates effective melt-based deposition of films with 568 nm absorption onset.

