Edge-Enriched Molybdenum Disulfide Ultrathin Nanosheets with a Widened Interlayer Spacing for Highly Efficient...

Transition metal sulfides have exhibited remarkable advantages in gaseous elemental mercury (Hg⁰) capture under high SO₂ atmosphere, whereas the weak thermal stability significantly inhibits their practical application. Herein, a novel N,N-dimethylformamide (DMF) insertion strategy via crystal growth engineering was developed to successfully enhance the Hg⁰ capture ability of MoS₂ at an elevated temperature for the first time. The DMF-inserted MoS₂ possesses an edge-enriched structure and an expanded interlayer spacing (9.8 Å) and can maintain structural stability at a temperature as high as 272 °C. The saturated Hg⁰ adsorption capacities of the DMF-inserted MoS₂ were measured to be 46.91 mg·g^-1 at 80 °C and 27.40 mg·g^-1 at 160 °C under high SO₂ atmosphere. The inserted DMF molecules chemically bond with MoS₂, which prevents possible structural collapse at a high temperature. The strong interaction of DMF with MoS₂ nanosheets facilitates the growth of abundant defects and edge sites and enhances the formation of Mo⁵⁺/Mo⁶⁺ and S₂^2- species, thereby improving the Hg⁰ capture activity at a wide temperature range. Particularly, Mo atoms on the (100) plane represent the strongest active sites for Hg⁰ oxidation and adsorption. The molecule insertion strategy developed in this work provides new insights into the engineering of advanced environmental materials.