Microwave-assisted quick synthesis of microcrystalline cellulose from black tea waste (Camellia sinensis) and...

Tea wastes generated in the industries during tea production processes show excellent potential to be used as a renewable, abundant, and cheap source for the extraction of microcrystalline cellulose. In the current work, MCC was isolated from black tea waste through microwave heating instead of using conventional heating and avoiding the traditional acid hydrolysis method. Microwave increased the reaction speed significantly and resulted in very quick delignification and bleaching of black tea waste to isolate MCC in white powdered form. FTIR, XRD, FESEM, and TGA analysis were then carried out to investigate the chemical functionality, crystallinity, morphology, and thermal properties, respectively, of the synthesized tea waste MCC. The characterization results demonstrated that cellulose with a short rough fibrous structure having an average particle size of around 23.06 μm was extracted. The results of FTIR and XRD demonstrated unequivocally that all amorphous non-cellulosic compounds had been eliminated. The microwave-extracted black tea waste MCC showed 89.77 % crystallinity and good thermal properties, indicating that it could be a promising filler material for preparing polymer composites. Therefore, microwave-assisted delignification and bleaching can be used as a suitable, energy-efficient, time-saving and low-cost method for extracting MCC from the black tea waste produced in tea factories.