Photoluminescence control by atomically precise surface metallization of C-centered hexagold(i) clusters using...

The properties of metal clusters are highly dependent on their molecular surface structure. The aim of this study is to precisely metallize and rationally control the photoluminescence properties of a carbon(C)-centered hexagold(i) cluster (CAu^I₆) using N-heterocyclic carbene (NHC) ligands with one pyridyl, or one or two picolyl pendants and a specific number of silver(i) ions at the cluster surface. The results suggest that the photoluminescence of the clusters depends highly on both the rigidity and coverage of the surface structure. In other words, the loss of structural rigidity significantly reduces the quantum yield (QY). The QY in CH₂Cl₂ is 0.04 for [(C)(Au^I-BIPc)₆Ag^I₃(CH₃CN)₃](BF₄)₅ (BIPc = N-isopropyl-N'-2-picolylbenzimidazolylidene), a significant decrease from 0.86 for [(C)(Au^I-BIPy)₆Ag^I₂](BF₄)₄ (BIPy = N-isopropyl-N'-2-pyridylbenzimidazolylidene). This is due to the lower structural rigidity of the ligand BIPc because it contains a methylene linker. Increasing the number of capping Ag^I ions, i.e., the coverage of the surface structure, increases the phosphorescence efficiency. The QY for [(C)(Au^I-BIPc²)₆Ag^I₄(CH₃CN)₂](BF₄)₆ (BIPc² = N,N'-di(2-pyridyl)benzimidazolylidene) recovers to 0.40, 10-times that of the cluster with BIPc. Further theoretical calculations confirm the roles of Ag^I and NHC in the electronic structures. This study reveals the atomic-level surface structure-property relationships of heterometallic clusters.