N,N-dicarboxymethyl Perylene-diimide-modified CdV2O6 Nanorods for Colorimetric Sensing of H₂O₂ and Pyrogallol

The peroxidase-like activity of CdV₂O₆ nanorods has been considerably improved by modification with N, N-dicarboxymethyl perylene-diimide (PDI) as a photosensitizer. The peroxidase-like behaviors are evaluated by virtue of the colorless chromogenic substrate 3,3',5,5'-tetramethylbenzidine (TMB), which is fast changed into blue oxTMB in the presence of H₂O₂ in only 90 s. PDI-CdV₂O₆ exhibits high stability at elevated temperatures and PDI-CdV₂O₆ retains more than 70% of its catalytic activity over a wide range of 15 to 60 °C. The catalytic mechanism of PDI-CdV₂O₆ is ascribed to the synergistic interaction between PDI and CdV₂O₆ and the generation of •O₂^- radicals. Based on the enhanced peroxidase-like activity of PDI-CdV₂O₆, a selective colorimetric sensor has been constructed for H₂O₂ and pyrogallol (PG) with detection limits of 36.5 μM and 0.179 μM, respectively. The feasibility of the proposed sensing platform has been validated by detecting H₂O₂ in milk and pyrogallol in tap water.