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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
Published on: December 20, 2016
Activation of trace LiNO3 additives by BF3 in high-concentration electrolytes towards stable lithium metal batteries
He-Yi Xia1, Yu-Ke Wang1, Zheng-Wen Fu1
1Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433, P. R. China. zwfu@fudan.edu.cn.
Abstract:
The activation of trace LiNO3 additives in high-concentration electrolytes is achieved by BF3 due to its Lewis acidity. This advanced electrolyte can promote the decomposition of LiNO3 into Li3N, attaining enhanced cycle reversibility of lithium anodes, which broadens the application of LiNO3 additives.
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