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Amidoboronates: bringing together the synthesis of BN-heterocycles via a reductive coupling and dynamic covalent
1Otto Diels Institute of Organic Chemistry, Kiel University, Otto-Hahn-Platz 4, Kiel 24098, Germany.
Abstract:
This Perspective describes how amidoboronates open up new chemical space spanning the areas of BN-heterocycles and dynamic covalent chemistry. BN-containing heterocycles offer the potential to access new properties and reactivity compared to their C-C analogues. Amidoboronates are introduced as a new class of B-N heterocycles that can be synthesised in three isomeric forms (meso5, rac5 and rac6) from the reductive coupling of N-aryl iminoboronates. Furthermore, initial investigations on the dynamic covalent chemistry of amidoboronates are discussed, such as the reversibility of C-C bond formation following the reductive coupling and tuning the rac5/rac6 ratio via dynamic covalent B-N and B-O bonds.
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