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Altering the spectroscopy, electronic structure, and bonding of organometallic curium(III) upon coordination of
Brian N Long1, María J Beltrán-Leíva1, Joseph M Sperling1
1Department of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, Tallahassee, FL, 32306, USA.
Abstract:
Structural and electronic characterization of (Cp'3Cm)2(μ-4,4'-bpy) (Cp' = trimethylsilylcyclopentadienyl, 4,4'-bpy = 4,4'-bipyridine) is reported and provides a rare example of curium-carbon bonding. Cp'3Cm displays unexpectedly low energy emission that is quenched upon coordination by 4,4'-bipyridine. Electronic structure calculations on Cp'3Cm and (Cp'3Cm)2(μ-4,4'-bpy) rule out significant differences in the emissive state, rendering 4,4'-bipyridine as the primary quenching agent. Comparisons of (Cp'3Cm)2(μ-4,4'-bpy) with its samarium and gadolinium analogues reveal atypical bonding patterns and electronic features that offer insights into bonding between carbon with f-block metal ions. Here we show the structural characterization of a curium-carbon bond, in addition to the unique electronic properties never before observed in a curium compound.
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