Photocatalytic H₂ Production by Visible Light on Cd_0.5Zn_0.5S Photocatalysts Modified with Ni(OH)₂ by Impregnation...

Nowadays, the study of environmentally friendly ways of producing hydrogen as a green energy source is an increasingly important challenge. One of these potential processes is the heterogeneous photocatalytic splitting of water or other hydrogen sources such as H₂S or its alkaline solution. The most common catalysts used for H₂ production from Na₂S solution are the CdS-ZnS type catalysts, whose efficiency can be further enhanced by Ni-modification. In this work, the surface of Cd_0.5Zn_0.5S composite was modified with Ni(II) compound for photocatalytic H₂ generation. Besides two conventional methods, impregnation was also applied, which is a simple but unconventional modification technique for the CdS-type catalysts. Among the catalysts modified with 1% Ni(II), the impregnation method resulted in the highest activity, for which a quantum efficiency of 15.8% was achieved by using a 415 nm LED and Na₂S-Na₂SO₃ sacrificial solution. This corresponded to an outstanding rate of 170 mmol H₂/h/g under the given experimental conditions. The catalysts were characterized by DRS, XRD, TEM, STEM-EDS, and XPS analyses, which confirmed that Ni(II) is mainly present as Ni(OH)₂ on the surface of the CdS-ZnS composite. The observations from the illumination experiments indicated that Ni(OH)₂ was oxidized during the reaction, and that it therefore played a hole-trapping role.