Superparamagnetic Spinel-Ferrite Nano-Adsorbents Adapted for Hg²⁺, Dy³⁺, Tb³⁺ Removal/Recycling: Synthesis,...

In the present work, superparamagnetic adsorbents based on 3-aminopropyltrimethoxy silane (APTMS)-coated maghemite (γFe₂O₃@SiO₂-NH₂) and cobalt ferrite (CoFe₂O₄@SiO₂-NH₂) nanoparticles were prepared and characterized using transmission-electron microscopy (TEM/HRTEM/EDXS), Fourier-transform infrared spectroscopy (FTIR), specific surface-area measurements (BET), zeta potential (ζ) measurements, thermogravimetric analysis (TGA), and magnetometry (VSM). The adsorption of Dy³⁺, Tb³⁺, and Hg²⁺ ions onto adsorbent surfaces in model salt solutions was tested. The adsorption was evaluated in terms of adsorption efficiency (%), adsorption capacity (mg/g), and desorption efficiency (%) based on the results of inductively coupled plasma optical emission spectrometry (ICP-OES). Both adsorbents, γFe₂O₃@SiO₂-NH₂ and CoFe₂O₄@SiO₂-NH₂, showed high adsorption efficiency toward Dy³⁺, Tb³⁺, and Hg²⁺ ions, ranging from 83% to 98%, while the adsorption capacity reached the following values of Dy³⁺, Tb³⁺, and Hg²⁺, in descending order: Tb (4.7 mg/g) > Dy (4.0 mg/g) > Hg (2.1 mg/g) for γFe₂O₃@SiO₂-NH₂; and Tb (6.2 mg/g) > Dy (4.7 mg/g) > Hg (1.2 mg/g) for CoFe₂O₄@SiO₂-NH₂. The results of the desorption with 100% of the desorbed Dy³⁺, Tb³⁺, and Hg²⁺ ions in an acidic medium indicated the reusability of both adsorbents. A cytotoxicity assessment of the adsorbents on human-skeletal-muscle derived cells (SKMDCs), human fibroblasts, murine macrophage cells (RAW264.7), and human-umbilical-vein endothelial cells (HUVECs) was conducted. The survival, mortality, and hatching percentages of zebrafish embryos were monitored. All the nanoparticles showed no toxicity in the zebrafish embryos until 96 hpf, even at a high concentration of 500 mg/L.