Pd-Ceria/CNMs Composites as Catalysts for CO and CH₄ Oxidation

The application of composite materials as catalysts for the oxidation of CO and other toxic compounds is a promising approach for air purification. In this work, the composites comprising palladium and ceria components supported on multiwall carbon nanotubes, carbon nanofibers and Sibunit were studied in the reactions of CO and CH₄ oxidation. The instrumental methods showed that the defective sites of carbon nanomaterials (CNMs) successfully stabilize the deposited components in a highly-dispersed state: PdO and CeO₂ nanoparticles, subnanosized PdO_x and Pd_xCe_1-xO_2-δ clusters with an amorphous structure, as well as single Pd and Ce atoms, are formed. It was shown that the reactant activation process occurs on palladium species with the participation of oxygen from the ceria lattice. The presence of interblock contacts between PdO and CeO₂ nanoparticles has an important effect on oxygen transfer, which consequently affects the catalytic activity. The morphological features of the CNMs, as well as the defect structure, have a strong influence on the particle size and mutual stabilization of the deposited PdO and CeO₂ components. The optimal combination of highly dispersed PdO_x and Pd_xCe_1-xO_2-δ species, as well as PdO nanoparticles in the CNTs-based catalyst, makes it highly effective in both studied oxidation reactions.