Synthesis and Evaluation of Engineering Properties of Polymer-Coated Glass Beads

Modern construction projects are often challenging, which has increased the demand for innovative materials that ensure improved safety, durability, and functionality. To explore the potential of enhancing soil material functionality, this study synthesized polyurethane on the surface of glass beads and evaluated their mechanical properties. The synthesis of polymer proceeded according to a predetermined procedure, where the polymerization was confirmed through analysis of chemical structure by Fourier transform infrared spectroscopy (FT-IR) and microstructure observation by a scanning electron microscope (SEM) after complete synthesis. The constrained modulus (M) and the maximum shear modulus (G) of mixtures with synthesized materials were examined by using an oedometer cell equipped with bender elements under a zero lateral strain condition. Both M and G decreased with an increase in the contents of polymerized particles due to a decrease in the number of interparticle contacts and contact stiffness induced by the surface modification. The adhesion property of the polymer induced a stress-dependent change in M but was observed to have little effect on G. Compared to the behavior of the rubber-sand mixtures, polymerized particles show the advantage of a smaller reduction of M.