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Related Concept Videos

Capacitor With A Dielectric01:18

Capacitor With A Dielectric

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Parallel plate capacitors consist of two conducting plates separated by a certain distance. However, it is mechanically difficult to hold the large plates parallel to each other without actual contact. Hence, a dielectric layer is commonly placed between the plates, which provides an easy solution for holding the plates together with a small gap and increases the capacitance of the capacitor.
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
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Synthesizing a Gel Polymer Electrolyte for Supercapacitors, Assembling a Supercapacitor Using a Coin Cell, and Measuring Gel Electrolyte Performance
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3D Printed Supercapacitor Exploiting PEDOT-Based Resin and Polymer Gel Electrolyte.

Valentina Bertana1, Giorgio Scordo2, Elena Camilli1

  • 1Department of Applied Science and Technology (DISAT), Polytechnic of Turin, Corso Duca degli Abruzzi 24, 10129 Torino, Italy.

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Summary

This study introduces a novel resin for 3D printing supercapacitors using stereolithography. The developed material enables the fabrication of functional energy storage devices with competitive energy density.

Keywords:
3D printingPEDOTenergy storagestereolithographysupercapacitors

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Additive Manufacturing

Background:

  • Growing demand for renewable energy and Internet of Things (IoT) devices necessitates advanced energy storage solutions.
  • Additive Manufacturing (AM) offers customization for portable energy storage, but resolution limitations exist with techniques like direct ink writing.
  • Micrometric precision is crucial for fabricating high-performance, miniaturized energy storage devices.

Purpose of the Study:

  • To develop and characterize a novel resin for stereolithography (SL) 3D printing of supercapacitors (SCs).
  • To create a printable, UV-curable conductive composite material for fabricating 3D energy storage electrodes.
  • To evaluate the electrical and electrochemical performance of 3D printed electrodes in an interdigitated device architecture.

Main Methods:

  • Development of a UV-curable conductive composite resin by mixing Poly(3,4-ethylenedioxythiophene) (PEDOT) with poly(ethylene glycol) diacrylate (PEGDA).
  • Fabrication of supercapacitor electrodes using a stereolithography (SL) 3D printing process with the developed resin.
  • Electrical conductivity measurements and electrochemical characterization of the 3D printed electrodes.

Main Results:

  • The developed resin exhibits electrical conductivity within the range of conductive polymers (200 mS/cm).
  • The 3D printed supercapacitor devices achieved an energy density of 0.68 µWh/cm², which is comparable to literature values.
  • The stereolithography process enabled the fabrication of functional electrodes with micrometric precision.

Conclusions:

  • A novel, printable, and UV-curable conductive resin was successfully developed for SL 3D printing of supercapacitors.
  • The developed material and process are suitable for fabricating functional energy storage devices with competitive performance.
  • This advancement holds potential for customized and portable energy storage solutions.