g-C₃N₄/MoO₃ composite with optimized crystal face: A synergistic adsorption-catalysis for boosting cathode...

The commercial application of lithium-sulfur batteries (LSBs) has been seriously hindered by the shuttle effect of lithium polysulfides (LiPSs) and their slow redox kinetics. In this work, g-C₃N₄/MoO₃ composed of graphite carbon nitride (g-C₃N₄) nanoflake and MoO₃ nanosheet is designed and applied to modify the separator. The polar MoO₃ can form chemical bond with LiPSs, effectively slowing down the dissolution of LiPSs. And based on the principle of "Goldilocks", LiPSs will be oxidized by MoO₃ to thiosulfate, which will promote the rapid conversion from long-chain LiPSs to Li₂S. Moreover, g-C₃N₄ can promote the electron transportation, and its high specific surface area can facilitate the deposition and decomposition of Li₂S. What's more, the g-C₃N₄ promotes the preferential orientation on the MoO₃(021) and MoO₃(040) crystal planes, which optimizes the adsorption capacity of g-C₃N₄/MoO₃ for LiPSs. As a result, the LSBs with g-C₃N₄/MoO₃ modified separator with a synergistic adsorption-catalysis, can achieve an initial capacity of 542 mAh g^-1 at 4C with capacity decay rate of 0.0053% per cycle for 700 cycles. This work achieves the synergy of adsorption and catalysis of LiPSs through the combination of two materials, providing a material design strategy for advanced LSBs.