Plutonium in sediments of the Eastern Guangdong coast-its sources and their contribution

The ^239+240Pu activities and ²⁴⁰Pu/²³⁹Pu atom ratios of surface sediments from the Eastern Guangdong coast (EGDC) were determined by sector field ICP-MS in order to examine the sources of plutonium (Pu) and quantify their contributions. The ^239+240Pu activities in the EGDC ranged from 0.113 to 0.451 Bq kg^-1, with an average of 0.225 ± 0.090 Bq kg^-1 (n = 17). Consistently high ²⁴⁰Pu/²³⁹Pu atom ratios, ranging from 0.218 to 0.274 (average = 0.254 ± 0.014, n = 17), indicate a non-global fallout Pu source in the EGDC. The horizontal distribution of the ²⁴⁰Pu/²³⁹Pu atom ratios in the EGDC sediment suggests the non-global fallout Pu is sourced from close-in fallout from the Pacific Proving Grounds (PPG). Using a simple two end-member mixing model, we calculated the relative proportions of Pu from the PPG and global fallout in the EGDC to be 57 ± 9 % and 43 ± 9 %, respectively. Moreover, from the well-defined relationship between ^239+240Pu activity and total organic carbon content in sediments and a two end-member mixing model using δ¹³C, we further calculated the Terr-global fallout (riverine input) and Mar-global fallout (direct atmospheric deposition) to be 11 ± 2 % and 32 ± 6 %, respectively. Finally, from the activity levels and atom ratios of Pu isotopes in the EGDC, we established a baseline for future use in environmental risk assessment related to nuclear power plant operations.