Optimizing adsorption performance of sludge-derived biochar via inherent moisture-regulated physicochemical...

Understanding the impact of abundant inherent moisture in sewage sludge on the physicochemical properties and adsorption applications of sludge-derived biochar (SDB) contributed significantly to promoting economical sludge reuse. The moisture (0-80%) contributed to the development of micropore and mesopore in SDB at 400 °C, resulting in a maximum increase in specific surface area (SSA) and total pore volume (TPV) of SDB by 38.47% (84.811-117.437 m²/g) and 92.60% (0.0905-0.1743 m³/g), respectively. At 600/800 °C, moisture only facilitated mesopore formation, while was exacerbated with increasing moisture content. Despite reduction in SSA during this stage, TPV increased by a maximum of 20.47% (0.1700-0.2048 m³/g). The presence of moisture during pyrolysis led to an increase in the formation of 3-5 thickened benzene rings and defective structures in SDB, along with more C=O, O-C=O/-OH, pyrrole N, pyridine N, and thiophene. As a result, moisture (40%/80%) increased the maximum adsorption capacity (76.2694-88.0448/90.1190 mg/g) of SDB (600 °C) for tetracycline, mainly due to enhanced pore filling effect and hydrogen bonding induced by improved physicochemical properties. This study offered a novel approach for optimizing the performance of SDB adsorption applications by manipulating the sludge moisture, which is critical for practical sludge management.