Tungsten Oxide-Based Z-Scheme for Visible Light-Driven Hydrogen Production from Water Splitting

The stoichiometric water splitting using a solar-driven Z-scheme approach is an emerging field of interest to address the increasing renewable energy demand and environmental concerns. So far, the reported Z-scheme must comprise two populations of photocatalysts. In the present work, only tungsten oxides are used to construct a robust Z-scheme system for complete visible-driven water splitting in both neutral and alkaline solutions, where sodium tungsten oxide bronze (Na_0.56WO_3-) is used as a H₂ evolution photocatalyst and two-dimensional (2D) tungsten trioxide (WO₃) nanosheets as an O₂ evolution photocatalyst. This system efficiently produces H₂ (14 μmol h^-1) and O₂ (6.9 μmol h^-1) at an ideal molar ratio of 2:1 in an aqueous solution driven by light, resulting in a remarkably high apparent quantum yield of 6.06% at 420 nm under neutral conditions. This exceptional selective H₂ and O₂ production is due to the preferential adsorption of iodide (I^-) on Na_0.56WO_3- and iodate (IO₃^-) on WO₃, which is evidenced by both experiments and density functional theory calculation. The present liquid Z-scheme in the presence of efficient shuttle molecules promises a separated H₂ and O₂ evolution by applying a dual-bed particle suspension system, thus a safe photochemical process.