Adsorption Performance of Magnetic Covalent Organic Framework Composites for Bisphenol A and Ibuprofen

As typical environmental endocrine disruptors and nonsteroidal anti-inflammatory drugs, bisphenol A and ibuprofen in water supplies can cause great harm to the ecological environment and human health. In this study, magnetic covalent organic framework composites Fe₃O₄@COF-300 were synthesized by the hydrothermal method and used to remove bisphenol A and ibuprofen from water. Fe₃O₄@COF-300 could be rapidly separated from the matrix by external magnetic fields, and could selectively adsorb bisphenol A and ibuprofen in the presence of coexisting compounds such as phenol, Congo red, and amino black 10B. The removal efficiency of ibuprofen was 96.12-98.52% at pH in the range of 2-4 and that of bisphenol A was 92.18-95.62% at pH in the range of 2-10. The adsorption of bisphenol A and ibuprofen followed a pseudo-second-order kinetic and Langmuir model, and was a spontaneous endothermic process with the maximum adsorption amounts of 173.31 and 303.03 mg∙g^-1, respectively. The material presented favorable stability and reusability, and the removal efficiency of bisphenol A and ibuprofen after 5 cycles was still over 92.15% and 89.29%, respectively. Therefore, the prepared composite Fe₃O₄@COF-300 exhibited good performance in the adsorption of bisphenol A and ibuprofen in water.