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Related Concept Videos

Capacitor With A Dielectric01:18

Capacitor With A Dielectric

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Parallel plate capacitors consist of two conducting plates separated by a certain distance. However, it is mechanically difficult to hold the large plates parallel to each other without actual contact. Hence, a dielectric layer is commonly placed between the plates, which provides an easy solution for holding the plates together with a small gap and increases the capacitance of the capacitor.
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
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Low-Loss Dielectric Ink for Printed Radio Frequency and Microwave Devices.

Yuri Piro1,2, Christopher Areias3,2, Andrew Luce3,2

  • 1Department of Chemistry, University of Massachusetts Lowell, Lowell, Massachusetts 01854, United States.

ACS Applied Materials & Interfaces
|July 14, 2023
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Summary

Researchers developed printable dielectric materials for radio frequency (RF) applications. These materials exhibit low dielectric loss and improved mechanical properties after heat treatment, enabling multilayer RF circuits.

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flexible electronicslow-loss dielectric materialshigh-frequency device packagingprinted electronicsring-opening metathesis polymerization

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Area of Science:

  • Materials Science
  • Polymer Chemistry
  • Electrical Engineering

Background:

  • Direct write printing of radio frequency (RF) components is limited by the availability of printable dielectric materials with suitable RF performance.
  • Existing RF laminates require high-resolution printing and specific dissipation factors crucial for advanced RF and microwave applications.

Purpose of the Study:

  • To develop novel dielectric materials for high-resolution direct write printing.
  • To achieve dielectric loss below 0.006 in the X and Ku frequency bands (8.2-18 GHz).
  • To ensure printability with low viscosity (<1000 cps) and a robust, low-temperature cure procedure.

Main Methods:

  • Ring-opening metathesis polymerization (ROMP) of 5-vinyl-2-norbornene using Grubbs catalyst (G-II) at room temperature.
  • Differential scanning calorimetry (DSC) to optimize catalyst activity and curing strategies.
  • Characterization of dielectric and mechanical properties before and after secondary heat treatment for multilayer integration.

Main Results:

  • Developed poly(5-vinyl-2-norbornene) with dielectric loss < 0.006 in X and Ku bands.
  • Achieved a 55.0% reduction in coefficient of thermal expansion (CTE) and increased glass-transition temperature (Tg) from 32.4 to 46.1 °C after secondary heat treatment.
  • Demonstrated successful integration into fully printed, multilayer RF applications with printed silver conductors.

Conclusions:

  • The developed dielectric material meets critical RF performance and printability requirements for direct write applications.
  • Post-printing heat treatment significantly enhances mechanical properties without compromising dielectric loss.
  • The material is suitable for fabricating advanced, printed multilayer RF circuits.