Comparative Study on Crystal Structures and Synthetic Techniques of Ternary Hafnium/Zirconium Fluorides

Mild hydrothermal synthesis was employed to grow high-quality single crystals of ternary fluoridohafnates at low temperatures. The series of new materials was characterized using single-crystal X-ray diffraction, and the crystal structures of AHfF₆ (A = Mg and Sr), A₂HfF₈ (A = Ba and Pb), Ca₅Hf₃F₂₂, and Cd₂HfF₈(H₂O)₆ are discussed herein. Although some material compositions have similar stoichiometries, all of the compositions adopt different structural motifs. A comparison of the crystal structures and synthesis techniques of ternary fluoridohafnates and ternary fluoridozirconates is also reported, and the impact of the subtle changes of synthesis conditions on overall structures is discussed.