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Updated: Jul 23, 2025

Time-resolved Photophysical Characterization of Triplet-harvesting Organic Compounds at an Oxygen-free Environment Using an iCCD Camera
Published on: December 27, 2018
Time-Dependent Colorful Circularly Polarized Organic Ultralong Room Temperature Phosphorescence from a
Lan Yu1, Zhisheng Gao1, He Cheng1
1Key Laboratory of Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Jiangsu National Synergistic Innovation Center for Advanced Materials (SICAM), Nanjing University of Posts & Telecommunications, 9 Wenyuan Road, Nanjing, 210023, China.
Abstract:
Colorful circularly polarized organic ultralong room temperature phosphorescence (CP-OURTP) materials have attracted much attention due to their superior optoelectronic properties for various applications. However, the development of colorful CP-OURTP materials in a single-component molecular system is currently facing great challenges. Herein, a feasible strategy is proposed to develop colorful CP-OURTP material from a single-component chiral molecule by introducing a chiral unit into the phosphorescence chromophore. A dual CP-OURTP band originated from inherent triplet excitons emission showing a lifetime of 946.44 ms and triplet-triplet annihilation induced delayed emission with a short lifetime of 209.91 ms as well as maximum asymmetry factors of ≈10-3 are realized. Owing to the changed OURTP intensity ratios between inherent CP-OURTP and delayed emission at different delayed times, time-dependent colorful CP-OURTP turned from yellow to green is obtained. This study provides a potential platform to prepare circularly polarized material systems showing colorful luminescent properties.
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