Estimation of diffusion time with the Shannon entropy approach
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Updated: Jul 23, 2025

In Situ Monitoring of Diffusion of Guest Molecules in Porous Media Using Electron Paramagnetic Resonance Imaging
Published on: September 2, 2016
Pablo M Cincotta1, Claudia M Giordano1
1Grupo de Caos en Sistemas Hamiltonianos, Facultad de Ciencias Astronómicas y Geofísicas, Universidad Nacional de La Plata and Instituto de Astrofísica de La Plata (CONICET), B1900FWA La Plata, B1900FWA, Argentina.
Abstract:
The present work revisits and improves the Shannon entropy approach when applied to the estimation of an instability timescale for chaotic diffusion in multidimensional Hamiltonian systems. This formulation has already been proved efficient in deriving the diffusion timescale in 4D symplectic maps and planetary systems, when the diffusion proceeds along the chaotic layers of the resonance's web. Herein the technique is used to estimate the diffusion rate in the Arnold model, i.e., of the motion along the homoclinic tangle of the so-called guiding resonance for several values of the perturbation parameter such that the overlap of resonances is almost negligible. Thus differently from the previous studies, the focus is fixed on deriving a local timescale related to the speed of an Arnold diffusion-like process. The comparison of the current estimates with determinations of the diffusion time obtained by straightforward numerical integration of the equations of motion reveals a quite good agreement.
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