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Is the surface of Hofmann-like spin-crossover {Fe(pz)[Pt(CN)4]} the same as its bulk?
Alejandro Martínez Serra1, Archit Dhingra1, María Carmen Asensio2,3
1Institut de Ciència dels Materials de la Universitat de València (ICMUV), University of Valencia, Carrer del Catedrátic José Beltrán Martinez, 2, 46980 Paterna, Valencia, Spain. archit.dhingra@uv.es.
Abstract:
Temperature dependent X-ray photoemission spectroscopy (XPS) has been employed to examine the spin-crossover (SCO) transition in the nanocrystals of 3D Hoffman-like {Fe(pz)[Pt(CN)4]}. Consistent with the existing literature, the temperature-dependent variations in the Fe 2p core-level spectrum provide unambiguous evidence of the spin-state transition in this SCO complex. One of the many possible reasons behind a lack of discernible temperature-driven shifts in the binding energies of both the N 1s core-level components could be the immunity of its HS electronic configuration to thermal fluctuations. The high-spin fraction versus temperature plot, extrapolated from the XPS measurements, reveals that the surface of the nanocrystals of {Fe(pz)[Pt(CN)4]} is in the high-spin state at room temperature, rendering it promising for room-temperature spintronics and quantum information science applications.
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