Selective heterogeneous capture and release of actinides using carborane-functionalized electrodes

We report the heterogenization of molecular, electrochemically switchable ortho-substituted carboranes (^POCb, ^POCb-Pyr) for selective metal capture. Films of ^POCb and ^POCb-Pyr on glassy carbon and carbon fiber (CF) electrodes demonstrated heterogeneous electrochemical behaviour that was enhanced by the inclusion of single-walled carbon nanotubes (CNTs). Galvanostatically charged CF|CNT|^POCb and CF|CNT|^POCb-Pyr electrodes selectively captured and released actinides (Th⁴⁺, UO₂²⁺) from mixed solutions containing alkali (Cs⁺), lanthanide (Nd³⁺, Sm³⁺) and actinide (Th⁴⁺, UO₂²⁺) metal ions.