Enhanced Oxygen Evolution Reaction Performance on NiS_x@Co₃O₄/Nickel Foam Electrocatalysts with Their Photothermal...

Based on the principle of heterogeneous catalysis for water electrolysis, electrocatalysts with appropriate electronic structure and photothermal property are expected to drive the oxygen evolution reaction effectively. Herein, amorphous NiS_x-coupled nanourchin-like Co₃O₄ was prepared on nickel foam (NiS_x@Co₃O₄/NF) and investigated as a electrocatalyst for photothermal-assisted oxygen evolution reaction. The experimental investigations and simulant calculations jointly revealed NiS_x@Co₃O₄/NF to be of suitable electronic structure and high near-infrared photothermal conversion capability to achieve the oxygen evolution reaction advantageously both in thermodynamics and in kinetics. Relative to Co₃O₄/NF and NiS_x/NF, better oxygen evolution reaction activity, kinetics, and stability were achieved on NiS_x@Co₃O₄/NF in 1.0 M KOH owing to the NiS_x/Co₃O₄ synergetic effect. In addition, the oxygen evolution reaction performance of NiS_x@Co₃O₄/NF can be obviously enhanced under near-infrared light irradiation, since NiS_x@Co₃O₄ can absorb the near-infrared light to produce electric and thermal field. For the photothermal-mediated oxygen evolution reaction, the overpotential and Tafel slope of NiS_x@Co₃O₄/NF at 50 mA cm^-2 were reduced by 23 mV and 13 mV/dec, respectively. The present work provides an inspiring reference to design and develop photothermal-assisted water electrolysis using abundant solar energy.