Single and multi-antibiotics removal via peroxymonosulfate activation using molybdenum disulfide (MoS₂): Central...

The efficacy of molybdenum disulfide (MoS₂) for the degradation of metronidazole (MET), tetracycline (TET), and ciprofloxacin (CIP) in single and multicomponent systems through peroxymonosulfate (PMS) activation was investigated. Several characterization techniques, such as SEM, XRD, XPS, and EPR were performed to understand the removal mechanism of the three antibiotics in PMS/MoS₂ system. In single component system with an initial antibiotic concentration of 10 mg L^-1, >95% removal of MET, TET, and CIP were observed within 60 min (PMS = 100 mg L^-1; MoS₂ = 0.5 g L^-1). It was observed that sulfate radical (SO₄^.-) and reactive ≡Mo- OOSO₃^- complex played a major role in the removal of antibiotics. Adsorption on MoS₂ and direct oxidation by PMS contributed to the removal of TET and CIP in MoS₂/PMS system. A Central composite design (CCD) with response surface methodology (RSM) was used to model the removal of MET, TET, and CIP in a multi-antibiotic system. The presence of multiple antibiotics affected the performance of MoS₂/PMS system as antibiotics competed for the adsorption sites on MoS₂ and the generated reactive species. CIP predominantly deterred the removal of both MET and TET. On the other hand, MET removal was decreased up to 25-40% in the presence of both TET and CIP. Similarly, TET removal decreased up to 15-20% in the presence of MET and CIP. CIP removal decreased up to 15-25% in the presence of MET and TET. In the presence of multiple antibiotics, the deterring effect of one pollutant over another can be overcome by increasing the MoS₂ concentration above 1200 mg L^-1 and PMS above 200 mg L^-1 to obtain 100% removal of all three pollutants. Overall, MoS₂ could be an ideal catalyst for the removal of antibiotics through PMS activation.