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Related Concept Videos

UV–Vis Spectrometers01:14

UV–Vis Spectrometers

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The absorbance of UV and visible (UV–visible) radiations is measured using a UV–visible spectrophotometer. Deuterium lamps, which emit UV radiation, and tungsten lamps, which produce radiation in the visible region, are used as light sources in UV–visible spectrophotometers. A monochromator or prism is used for diffraction grating, i.e., to split the incoming radiation into different wavelengths. A system of slits is used to focus the desired wavelength on the sample cell.
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IR Spectrometers01:25

IR Spectrometers

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There are two main infrared (IR) spectrophotometers: dispersive IR spectrometers and Fourier transform infrared (FTIR) spectrometers. In a dispersive IR spectrometer, a beam of infrared radiation produced by a hot wire is divided into two parallel equal-intensity beams using mirrors. One beam passes through the sample, while another is a reference beam. The beams then move through the monochromator, which separates the radiations into a continuous spectrum of different frequencies. The...
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Ultraviolet and Visible (UV–Vis) Spectroscopy: Overview01:02

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Ultraviolet–visible (UV–visible or UV–Vis) spectroscopy is an analytical technique that investigates the interaction between matter and UV–Vis light within the electromagnetic spectrum. This method is widely used for its versatility, simplicity, and relatively quick data acquisition, making it valuable for both qualitative and quantitative analysis. When UV–Vis radiation passes through a material,  molecules absorb light depending on the energy required for...
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UV–Vis Spectroscopy: Woodward–Fieser Rules01:29

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UV–Visible absorption spectra of conjugated dienes arise from the lowest energy π → π* transitions. The light-absorbing part of the molecule is called the chromophore, and the substituents directly attached to the chromophore are called auxochromes. A strong correlation exists between the absorption maxima, λmax, and the structure of a conjugated π system. The Woodward–Fieser rules predict the value of λmax for a given...
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Atomic Absorption Spectroscopy: Instrumentation01:22

Atomic Absorption Spectroscopy: Instrumentation

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An atomic absorption spectrophotometer (AAS) comprises several components: a radiation source, an atomizer, a monochromator, and a detector. The radiation source can be a hollow-cathode lamp (HCL) or an electrodeless-discharge lamp (EDL), both of which provide a narrow emission line of the required wavelength. However, some instruments use continuum sources and high-resolution monochromators to achieve a narrow range of radiation.
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Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation01:26

Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation

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Inductively coupled plasma (ICP) is the common plasma source used in atomic emission spectroscopy (AES), a technique that detects and analyzes various elements in a sample. This method is often called inductively coupled plasma atomic emission spectroscopy (ICP-AES).
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Lightweight computational spectrometer enabled by learned high-correlation optical filters.

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    A novel neural network-gradient projection for sparse reconstruction (NN-GPSR) spectrometer achieves high spectral accuracy with reduced storage. This method utilizes NN-learned filters, overcoming limitations of conventional techniques for efficient embedded systems.

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    Area of Science:

    • Spectroscopy
    • Computational Imaging
    • Machine Learning

    Background:

    • Neural network (NN) spectrometers offer high accuracy but demand significant storage.
    • Conventional gradient projection for sparse reconstruction (GPSR) algorithms require less storage but yield lower spectral accuracy.
    • GPSR performance is limited by optical filter properties, complicating design and fabrication.

    Purpose of the Study:

    • To develop a computational spectrometer with both high spectral reconstruction accuracy and reduced storage requirements.
    • To leverage neural networks for improved optical filter design in spectral reconstruction.

    Main Methods:

    • Implementation of a hybrid approach, NN-GPSR, combining NN-learned filters with an optimized GPSR algorithm.
    • NN-learned filters act as an encoder, exploiting high correlation for efficient data representation.
    • An optimized GPSR algorithm functions as the decoder, enabling precise spectral reconstruction.

    Main Results:

    • The NN-GPSR method demonstrates high-precision spectral reconstruction capabilities.
    • NN-GPSR significantly reduces the storage requirements compared to traditional NN spectrometers.
    • The approach effectively utilizes prior knowledge from extensive image datasets for optical filter design.

    Conclusions:

    • NN-GPSR offers a superior alternative for computational spectroscopy in embedded systems.
    • This hybrid method balances accuracy and efficiency, overcoming limitations of existing techniques.
    • NN-learned filters are key to achieving high performance with reduced computational load.