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Elastocaloric Effect in Graphene Kirigami.

Luiz A Ribeiro Junior1,2, Marcelo L Pereira Junior3, Alexandre F Fonseca4

  • 1Institute of Physics, University of Brasília, 70910-900 Brasília, Brazil.

Nano Letters
|July 21, 2023
PubMed
Summary
This summary is machine-generated.

Graphene kirigami (GK) exhibits significant elastocaloric effects, showing a large temperature change for cooling and heating. This research explores GK

Keywords:
Coefficient of PerformanceElastocaloric EffectGraphene KirigamiMolecular Dynamics

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Thermodynamics

Background:

  • Kirigami, the art of paper cutting, inspires kirigami-based materials (KMs) with unique elastocaloric effects (ECE).
  • Nanoscale graphene kirigami (GK) has been experimentally realized, presenting an opportunity to study ECE in the thinnest possible KM.

Purpose of the Study:

  • To investigate the elastocaloric effect in graphene kirigami (GK).
  • To analyze the temperature change and coefficient of performance (COP) in GK using molecular dynamics simulations.

Main Methods:

  • Molecular dynamics simulations were employed to study GK.
  • Analysis focused on temperature change and coefficient of performance (COP) under applied strain.

Main Results:

  • Graphene kirigami demonstrated a substantial temperature change: 9.32 K for heating and -3.50 K for cooling.
  • This temperature change is significantly higher (23 times) than that observed in macroscopic kirigami-based materials.
  • Reasonable coefficient of performance (COP) values of approximately 1.57 (heating) and 0.62 (cooling) were achieved.

Conclusions:

  • Graphene kirigami exhibits a significant elastocaloric effect, making it a promising material for thermal management applications.
  • The one-atom-thick nature of graphene prevents complex temperature distributions seen in larger KMs, simplifying analysis and potentially enhancing performance.