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Updated: Aug 5, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Thiadiazole-Derived Covalent Organic Framework Macroscopic Ultralight Aerogel
Haifeng Ji1, Mengke Li1, Gaojie Yan1
1Hebei Key Laboratory of Functional Polymers, Department of Polymer Materials and Engineering, Hebei University of Technology, Tianjin 300401, P. R. China.
Abstract:
Shaping covalent organic frameworks (COFs) into macroscopic objects for practical application remains a huge challenge. Herein, a new thiadiazole-derived COF macroscopic ultralight aerogel (NNS-VCOF) was prepared through acid-catalyzed aldol condensation between 2,5-dimethyl-1,3,4-thiadiazole and a tritopic aromatic aldehyde derivative. NNS-VCOF aerogel shows extremely low density (ca. 0.020 g cm-3), excellent mechanical properties (compression modulus of 16.65 kPa), thermal insulation properties (low thermal conductivity of 0.03270 W m-1 K-1 at 25 °C), and flame retardancy (quickly self-extinguishing after ignition) due to its three-dimensional sponge-like architecture and special nitrogen heterocyclic framework. To our delight, NNS-VCOF aerogel not only can be used as an outstanding macroscopic material but also shows efficient photocatalytic hydrogen evolution properties in a powder state because of the superhydrophilicity and appropriate optical properties.
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