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Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
Shear-induced criticality in glasses shares qualitative similarities with the Gardner phase
Norihiro Oyama1,2, Hideyuki Mizuno1, Atsushi Ikeda1,3
1Graduate School of Arts and Sciences, The University of Tokyo, Tokyo 153-8902, Japan. oyamanorihiro0215@gmail.com.
Abstract:
Although glass phases are ubiquitously found in various soft matter systems, we are still far from a complete understanding of them. The concept of marginal stability predicted by infinite-dimensional mean-field theories is drawing attention as a candidate for a universal and distinguishing unique feature of glasses. While among theoretical predictions, the non-Debye scaling has indeed been observed universally over various classes of glasses, the Gardner phase is found only in a limited portion of them. In this work, we numerically demonstrate that plastic events observed in two-dimensional Lennard-Jones glasses under quasistatic shear exhibit statistical properties that are qualitatively consistent with the picture of an infinitely hierarchical energy landscape associated with the Gardner phase.
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To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
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