Cu-Based Bimetallic Catalysts for Electrocatalytic Oxidative Dehydrogenation of Furfural with Practical Rates
Hengzhou Liu1, Jiaqi Yu2, Yifu Chen1
1Department of Chemical and Biological Engineering, Iowa State University, 618 Bissell Road, Ames, Iowa 50011, United States.
Abstract:
Electrocatalytic oxidative dehydrogenation (EOD) of aldehydes enables ultra-low voltage, bipolar H2 production with co-generation of carboxylic acid. Herein, we reported a simple galvanic replacement method to prepare CuM (M = Pt, Pd, Au, and Ag) bimetallic catalysts to improve the EOD of furfural to reach industrially relevant current densities. The redox potential difference between Cu/Cu2+ and a noble metal M/My+ can incorporate the noble metal on the Cu surface and enlarge its surface area. Particularly, dispersing Pt in Cu (CuPt) achieved a record-high current density of 498 mA cm-2 for bipolar H2 production at a low cell voltage of 0.6 V and a Faradaic efficiency of >80% to H2. Future research is needed to deeply understand the synergistic effects of Cu-M toward EOD of furfural, and improve the Cu-M catalyst stability, thus offering great opportunities for future distributed manufacturing of green hydrogen and carbon chemicals with practical rates and low-carbon footprints.
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