Coupling Carbon-Based Composite Phase Change Materials with a Polyurethane Sponge for Sustained and Efficient...

The efficient cleanup of crude oil spills is a worldwide problem due to their high viscosity and low fluidity. Under the assistance of solar radiation, adsorbents with in situ heating function are becoming the ideal candidates to solve this problem. In this study, a new strategy coupling a polyurethane (PU) sponge with phase change materials (PCMs) is proposed to realize the efficient utilization of solar energy and crude oil cleanup. Wormlike carbon nanotubes/mesoporous carbon (CNTs/MC) with a core-shell structure was used to encapsulate polyethylene glycol (PEG), which was then introduced into the PU sponge for photothermal conversion and thermal storage. After coating with a polydimethylsiloxane (PDMS) layer, the sponge was further endowed with hydrophobic characteristics. Additionally, PDMS can function as a binder between PEG@CNTs/MC and sponge skeleton. The resulting PEG@CNTs/MC/PU/PDMS (named as PEG@CMPP) exhibited excellent photothermal conversion and high absorption capacity for high-viscosity crude oil. Most importantly, thanks to the heat storage properties of PEG, the stored heat can be sustainably transferred to the surrounding crude oil to promote its continuous absorption even under insufficient light intensity conditions. The crude oil absorption capacity of PEG@CMPP-3 reached approximately 0.96 g/cm³ even after the light source was removed, which manifested the distinctive advantages compared to the conventional photothermal adsorbent. The proposed approach integrates the high efficiency of solar-assisted heating and energy-conserving advantage, thereby providing a feasible strategy for highly efficient remediation of viscous crude oil spills.