Development of Membrane Reactor Coupling Hydrogen and Syngas Production

Simultaneous syngas and pure hydrogen production through partial oxidation of methane and water splitting, respectively, were demonstrated by using mixed ionic-electronic conductors. Tubular ceramic membranes prepared from La_0.5Sr_0.5FeO₃ perovskite were successfully utilized in a 10 M lab scale reactor by applying a radial arrangement. The supply of methane to the middle area of the reaction zone was shown to provide a uniform distribution of the chemical load along the tubes' length. A steady flow of steam feeding the inner part of the membranes was used as oxidative media. A described configuration was found to be favorable to maintaining oxygen permeability values exceeding 1.1 mL∙cm^-2∙min^-1 and long-term stability of related functional characteristics. Methane's partial oxidation reaction assisted by 10%Ni@Al₂O₃ catalyst proceeded with selectivity values above 90% and conversion of almost 100%. The transition from a laboratory model of a reactor operating on one tubular membrane to a ten-tube one resulted in no losses in the specific performance. The optimized supply of gaseous fuel opens up the possibility of scaling up the reaction zone and creating a promising prototype of a multitubular reaction zone with a simplified sealing procedure.