Tough polyvinyl alcohol-gelatin biological macromolecules ionic hydrogel temperature, humidity, stress and strain,...

High strength, high toughness and high sensitivity were some of the most popular characteristics of flexible sensors. However, the mechanical properties and reproducibility of current single biomacromolecule gelatin hydrogel sensors are lower, and few hydrogel sensors have been able to provide excellent mechanical properties and flexibility at the same time so far. To address this challenge, a simple method to prepare tough polyvinyl alcohol (PVA) and gelatin hydrogel was proposed in this study. The PVA-gelatin-Fe³⁺ biological macromolecules hydrogel was prepared by a freeze-casting-assisted solution substitution method, which exhibited high strength (2.5 MPa), toughness (7.22 MJ m^-3), and excellent temperature, humidity, stress, strain, and human motion sensing properties. This combination of mechanical properties and flexibility makes PVA-gelatin biological macromolecules hydrogel a promising material for flexible sensing. In addition, an ionic immersion strategy could also impart multiple functions to the hydrogel and be applied to various hydrogel sensor materials. Thus, this work provided an all-around solution for the preparation of advanced and robust sensors with good application prospects.