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Related Concept Videos

Metallic Solids02:37

Metallic Solids

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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
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Spark Plasma Sintering Apparatus Used for the Formation of Strontium Titanate Bicrystals
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Programming Crystallographic Orientation in Additive-Manufactured Beta-Type Titanium Alloy.

Xuan Luo1,2,3, Tao Song1, Annett Gebert2

  • 1National Engineering Research Center of Near-net-shape Forming for Metallic Materials, Guangdong Provincial Key Laboratory for Processing and Forming of Advanced Metallic Materials, South China University of Technology, Guangzhou, 510640, China.

Advanced Science (Weinheim, Baden-Wurttemberg, Germany)
|July 28, 2023
PubMed
Summary

This study introduces a new method called multitrack coupled directional solidification (MTCDS) to control crystal growth in 3D-printed titanium alloys. By carefully managing the way metal melts and solidifies during printing, the researchers were able to program the crystal structure along any desired direction. This is important because the crystal structure affects the material's properties, like how stiff or flexible it is. The method was tested on a type of titanium alloy used in medical applications and successfully produced a consistent crystal orientation with a low elastic modulus. The researchers suggest this technique could be used more broadly to customize material properties in additive manufacturing.

Keywords:
additive manufacturingcrystallographic orientationdirectional solidificationpropertiesadditive manufacturingdirectional solidificationtitanium alloyscrystallographic orientation

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Area of Science:

  • Additive manufacturing materials science
  • Crystallography in metallurgy
  • Biomedical materials engineering

Background:

Additive manufacturing processes often result in predictable crystallographic orientations in metallic materials. These orientations typically align with the build direction, such as <001> or <110>. Prior research has shown that such orientations influence mechanical properties like elastic modulus. However, a gap remains in the ability to program crystallographic orientation along arbitrary 3D directions. This uncertainty drives the need for new methods to control crystal growth during solidification. Existing approaches lack precision in tailoring orientations beyond the build axis. No prior work has resolved how to achieve this in biomedical alloys. The challenge is to develop a technique that allows for such control. This paper addresses that specific limitation in LPBF processes.

Purpose Of The Study:

The aim of this study is to develop a method for programming crystallographic orientation in additive-manufactured materials along arbitrary 3D directions. The focus is on biomedical beta-type Ti-Nb-Zr-Ta alloys, which are known for their low elastic modulus. The motivation is to enable the customization of mechanical properties through controlled crystal growth. The study seeks to overcome the limitations of conventional directional solidification techniques. It also aims to demonstrate how this can be achieved using laser powder bed fusion. The goal is to establish a reproducible and generalizable method for orientation programming. This approach could expand the application of additive manufacturing in biomedical contexts. The study is driven by the need for precise material property control.

Main Methods:

The study introduces a technique called multitrack coupled directional solidification (MTCDS). This method involves directional solidification of coupled multi-track melt pools. The process is guided by a specific temperature gradient direction. The technique is applied to beta-type Ti-Nb-Zr-Ta alloys using laser powder bed fusion. The orientation of the melt pools is carefully controlled to influence crystal growth. The β-Ti phase is observed to undergo continuous epitaxial growth. This results in the desired <001> orientation along arbitrary 3D directions. The method is tested and validated through material characterization and crystallographic analysis.

Main Results:

The MTCDS technique successfully programs the <001> crystallographic orientation along arbitrary 3D directions. This is achieved through controlled directional solidification of multi-track melt pools. The β-Ti phase exhibits continuous epitaxial growth under the specific temperature gradient. Elastic modulus values of approximately 60 ± 1.2 GPa are customized along the chosen direction. The method allows for precise orientation control in biomedical beta-type Ti alloys. The results demonstrate the feasibility of programming crystallographic orientation in 3D. The technique is shown to be effective in tailoring material properties. These findings suggest potential for broader application in additive manufacturing.

Conclusions:

The authors propose that MTCDS is a viable method for programming crystallographic orientation in additive-manufactured materials. The technique allows for the customization of <001> orientation along arbitrary 3D directions. This is achieved through directional solidification of multi-track melt pools. The β-Ti phase undergoes continuous epitaxial growth as a result. Elastic modulus values are successfully tailored to approximately 60 ± 1.2 GPa. The method is demonstrated to be effective in biomedical beta-type Ti-Nb-Zr-Ta alloys. The authors suggest that MTCDS can be generalized to other metallic materials. The findings indicate potential for tailoring properties in a wide range of applications.

MTCDS uses directional solidification of multi-track melt pools with a specific temperature gradient. This promotes continuous epitaxial growth of the β-Ti phase.

MTCDS couples multiple melt pools and controls the temperature gradient to program orientation along arbitrary 3D directions, unlike conventional methods limited to build direction.

The β-Ti phase undergoes continuous epitaxial growth during MTCDS, enabling the desired <001> orientation along arbitrary directions.

Customizing the elastic modulus to approximately 60 ± 1.2 GPa demonstrates the ability to tailor material properties via orientation programming.

The temperature gradient direction is specifically controlled to guide the epitaxial growth of the β-Ti phase along arbitrary 3D directions.

The authors propose that MTCDS can be applied to a wide range of metallic materials to program crystallographic orientations and tailor properties.