Electron Transfer in Contact Electrification under Different Atmospheres Packaged inside TENG

Contact electrification (CE), a common physical phenomenon, is worth discussing. However, there are few reports on the influence of atmosphere on CE, or on the performance of triboelectric nanogenerators (TENG), based on CE by encapsulating gas inside. Here, we propose physical processes of electron transfer to interpret the impact of the gaseous atmosphere on CE. An atmosphere-filled triboelectric nanogenerator (AF-TENG) encapsulated five different gas-components of air based on the vertical contact separation mode was prepared. The sensitivity (1.02 V·N^-1) and the power density (9.63 μW·m^-2) of the oxygen-atmosphere-filled AF-TENG were 229.03% and 157.81% higher than these (0.31 V·N^-1 and 3.84 μW·m^-2) of the nitrogen-atmosphere-filled AF-TENG. As the oxygen atom possesses more atomic energy levels than other atoms, this could act as a "bridge" for more electrons to directly transfer between the two materials. The device package under different atmospheres could not only strengthen understanding of CE and improve the performance of TENG, but also be potentially applicable to prevent and control unnecessary damage caused by static electricity.