Deep Eutectic Solvents: Properties and Applications in CO₂ Separation

Nowadays, many researchers are focused on finding a solution to the problem of global warming. Carbon dioxide is considered to be responsible for the "greenhouse" effect. The largest global emission of industrial CO₂ comes from fossil fuel combustion, which makes power plants the perfect point source targets for immediate CO₂ emission reductions. A state-of-the-art method for capturing carbon dioxide is chemical absorption using an aqueous solution of alkanolamines, most frequently a 30% wt. solution of monoethanolamine (MEA). Unfortunately, the usage of alkanolamines has a number of drawbacks, such as the corrosive nature of the reaction environment, the loss of the solvent due to its volatility, and a high energy demand at the regeneration step. These problems have driven the search for alternatives to that method, and deep eutectic solvents (DESs) might be a very good substitute. Many types of DESs have thus far been investigated for efficient CO₂ capture, and various hydrogen bond donors and acceptors have been used. Deep eutectic solvents that are capable of absorbing carbon dioxide physically and chemically have been reported. Strategies for further CO₂ absorption improvement, such as the addition of water, other co-solvents, or metal salts, have been proposed. Within this review, the physical properties of DESs are presented, and their effects on CO₂ absorption capacity are discussed in conjunction with the types of HBAs and HBDs and their molar ratios. The practical issues of using DESs for CO₂ separation are also described.