MoS₂-Based Nanocomposites for Photocatalytic Hydrogen Evolution and Carbon Dioxide Reduction

Photocatalysis is a facile and sustainable approach for energy conversion and environmental remediation by generating solar fuels from water splitting. Due to their two-dimensional (2D) layered structure and excellent physicochemical properties, molybdenum disulfide (MoS₂) has been effectively utilized in photocatalytic H₂ evolution reaction (HER) and CO₂ reduction. The photocatalytic efficiency of MoS₂ greatly depends on the active edge sites present in their layered structure. Modifications like reducing the layer numbers, creating defective structures, and adopting different morphologies produce more unsaturated S atoms as active edge sites. Hence, MoS₂ acts as a cocatalyst in nanocomposites/heterojunctions to facilitate the photogenerated electron transfer. This review highlights the role of MoS₂ as a cocatalyst for nanocomposites in H₂ evolution reaction and CO₂ reduction. The H₂ evolution activity has been described comprehensively as binary (with metal oxide, carbonaceous materials, metal sulfides, and metal-organic frameworks) and ternary composites of MoS₂. Photocatalytic CO₂ reduction is a more complex and challenging process that demands an efficient light-responsive semiconductor catalyst to tackle the thermodynamic and kinetic factors. Photocatalytic reduction of CO₂ using MoS₂ is an emerging topic and would be a cost-effective substitute for noble catalysts. Herein, we also exclusively envisioned the possibility of layered MoS₂ and its composites in this area. This review is expected to furnish an understanding of the diverse roles of MoS₂ in solar fuel generation, thus endorsing an interest in utilizing this unique layered structure to create nanostructures for future energy applications.