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Alcohols from Carbonyl Compounds: Reduction02:23

Alcohols from Carbonyl Compounds: Reduction

Reduction is a simple strategy to convert a carbonyl group to a hydroxyl group. The three major pathways to reduce carbonyls to alcohols are catalytic hydrogenation, hydride reduction, and borane reduction.
Catalytic hydrogenation is similar to the reduction of an alkene or alkyne by adding H2 across the pi bond in the presence of transition metal catalysts like Raney Ni, Pd–C, Pt, or Ru. Aldehydes and ketones can be reduced by this method, often under mild to moderate heat (25–100°C) and...
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The Carbon Cycle01:14

The Carbon Cycle

Carbon is the basis of all organic matter on Earth, and is recycled through the ecosystem in two primary processes: one in which carbon is exchanged among living organisms, and one in which carbon is cycled over long periods of time through fossilized organic remains, weathering of rocks, and volcanic activity. Human activities, including increased agricultural practices and the burning of fossil fuels, has greatly affected the balance of the natural carbon cycle.
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Softwoods and Hardwoods01:28

Softwoods and Hardwoods

Softwoods and hardwoods, derived from different types of trees, are distinguished by their leaf structures and cellular compositions, each serving unique purposes in construction and manufacturing. Softwoods come from cone-bearing trees with needle-like leaves and are predominantly composed of longitudinal cells called tracheids and a smaller proportion of radial cells known as rays. Due to their cellular structure, softwoods are commonly used in construction for structural frames, sheathing,...
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The Calvin Benson Cycle01:46

The Calvin Benson Cycle

Ribulose 1,5- bisphosphate carboxylase/oxygenase (RuBisCo) is a critical enzyme that catalyzes carbon dioxide assimilation during photosynthesis. However, it is an inefficient enzyme, having an extremely slow catalytic rate. A typical enzyme can process about a thousand molecules per second; however, RuBisCo fixes only around three-carbon dioxides per second. Photosynthetic cells compensate for this slow rate by synthesizing very high amounts of RuBisCo, making it the most abundant single...
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Lumber01:19

Lumber

Lumber is derived from logs which are harvested, debarked, and processed into long pieces with a rectangular cross-section. The transformation of logs into lumber involves multiple steps, beginning with an automated saw that slices the log into slabs. These slabs are then transported via a conveyor belt to smaller saws, where they are cut into square-edged pieces of specific widths.
Initially, the surfaces of these lumber pieces are rough, and their dimensions may vary slightly from one end to...
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Benzene to 1,4-Cyclohexadiene: Birch Reduction Mechanism01:18

Benzene to 1,4-Cyclohexadiene: Birch Reduction Mechanism

Birch reduction uses solvated electrons as reducing agents. The reaction converts benzene to 1,4-cyclohexadiene. The reaction proceeds by the transfer of a single electron to the ring to form a benzene radical anion. This anion is highly basic—it abstracts a proton from the alcohol to form a cyclohexadienyl radical. Another single electron transfer gives the cyclohexadienyl anion. A proton transfer from the alcohol forms 1,4-cyclohexadiene. Since this reduction occurs via radical anion...
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