Green-Processed Non-Fullerene Organic Solar Cells Based on Y-Series Acceptors

The development of environmentally friendly and sustainable processes for the production of high-performance organic solar cells (OSCs) has become a critical research area. Currently, Y-series electron acceptors are widely used in high-performance OSCs, achieving power conversion efficiencies above 19%. However, these acceptors have large fused conjugated backbones that are well-soluble in halogenated solvents, such as chloroform and chlorobenzene, but have poor solubility in non-halogenated green solvents. To overcome this challenge, recent studies have focused on developing green-processed OSCs that use non-chlorinated and non-aromatic solvents to dissolve bulk-heterojunction photoactive layers based on Y-series electron acceptors, enabling environmentally friendly fabrication. In this comprehensive review, an overview of recent progress in green-processed OSCs based on Y-series acceptors is provided, covering the determination of Hansen solubility parameters, the use of non-chlorinated solvents, and the dispersion of conjugated nanoparticles in water/alcohol. It is hoped that the timely review will inspire researchers to develop new ideas and approaches in this important field, ultimately leading to the practical application of OSCs.