Preparation and application of irradiated polyvinyl alcohol/starch/pumice composites for adsorption of basic dye:...

Even at low concentrations, organic dye pollution entering water resources from the textile, paper, and pharmaceutical industry sectors poses a serious hazard to human and aquatic life. One of the most significant remediation methods is the adsorption method. In the present study, the uptake of basic violet 7 (BV7) synthetic dye was investigated utilizing Poly (vinyl alcohol)/starch/Pumice [poly (PVA/St/Pu)] composite films prepared by a simple casting of both PVA and St with Pu and then irradiated by electron beam (EB) source to prompt curing. Numerous characterization methods, such as SEM, FTIR, X-ray diffraction (XRD, and other measurements, were examined on the prepared sample. The tensile strength (TS) of all composites was increased by increasing the radiation dose up to 10 kGy. TS was increased by 3 php of Pu, and an overload of Pu led to a decrease in TS values. The elongation at break (E_b) of the prepared composite increased at 3 Pu, then decreased as the quantity of the pumice increased, while the E_b was decreased by irradiation. The effects of the produced polymeric films' composition and irradiation dose on the basic violet 7 (BV 7) dye adsorption were studied. It was found that the adsorption capacity of poly (PVA/St/9 php Pu-10 kGy) toward the BV 7 dye was 64.9 mg/g at the optimal conditions: pH = 11, contact time = 480 min., adsorbent dosage = 0.2 g., concentration = 150 mg/l, and temperature = 298 K. The adsorption process fitted with the pseudo-second-order model, Freundlich adsorption isotherms were found to be spontaneous and endothermic.