Universal Water Disinfection by the Introduction of Fe-N₃ Traps between g-C₃N₄ Layers under Visible Light

Efficient inactivation of bacteria in the sewage via a photocatalytic process represents a promising strategy for the efficient chemical utilization of solar energy. Herein, uniformly dispersed Fe atoms were embedded between layers of g-C₃N₄ photocatalysts (CNFx), which were facilely prepared by thermal treatment. The optimized photocatalyst (CNF₁₀₀) first showed excellent photoactivity for killing a variety of bacteria (93.0% for E. coli, 93.9% for Salmonella, and 96.2% for S. aureus) under visible light irradiation. The superior activity can be attributed to the formation of shallow electron traps (Fe-N₃) that can capture excitons of excited states, which promote the charge transfer and energy transfer process of activated adsorbed molecular oxygen, respectively, forming reactive oxygen species, improving separation efficiency of photoexcited electrons and holes, and the Fe-N₃ traps can also be used as photosensitive sites to broaden the absorption range of visible light. This strategy of constructing shallow electronic traps lays a theoretical foundation for the design of new environmentally friendly and efficient water disinfectants.