Multifunctional amorphous FeCoNiTiSi high-entropy alloys with excellent electromagnetic-wave absorption performances

Amorphous high-entropy alloys (HEAs) as electromagnetic-wave absorbing materials have been rarely reported. In this work, amorphous FeCoNiTiSi HEAs were synthesized by introducing a high content of large-atom Ti using the high-energy ball-milling technique. This amorphous structure could improve the saturated magnetization and coercivity of HEAs, but slightly degraded the mechanical and oxidation resistance properties. In terms of electromagnetic properties, FeCoNiTi_0.01Si and FeCoNiTiSi exhibit excellent electromagnetic-wave absorption performances, with significant absorptions of -68.4 dB at 6.14 GHz and -63.4 dB at 9.12 GHz, corresponding to bandwidths of 5.15 GHz (1.69 mm) and 3.64 GHz (1.43 mm), respectively. Overall, the prepared FeCoNiTiSi HEAs exhibited superior comprehensive performances compared to other HEA absorption materials. This work provided a novel strategy for the development of new electromagnetic-wave absorption materials with low weight, high absorption efficiency, and resistance to harsh environments.