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Updated: Jul 19, 2025

Measuring Magnetically-Tuned Ferroelectric Polarization in Liquid Crystals
Published on: August 15, 2018
Lamellar Fluctuations Melt Ferroelectricity
G G Guzmán-Verri1, C H Liang2, P B Littlewood3
1Centro de Investigación en Ciencia e Ingeniería de Materiales, Universidad de Costa Rica, San José 11501, Costa Rica; Escuela de Física, Universidad de Costa Rica, San José 11501, Costa Rica; and Department of Materials Science and Metallurgy, University of Cambridge, Cambridge CB3 0FS, United Kingdom.
Abstract:
We consider a standard Ginzburg-Landau model of a ferroelectric whose electrical polarization is coupled to gradients of elastic strain. At the harmonic level, such flexoelectric interaction is known to hybridize acoustic and optic phonon modes and lead to phases with modulated lattice structures that precede the state with spontaneously broken inversion symmetry. Here, we use the self-consistent phonon approximation to calculate the effects of thermal and quantum polarization fluctuations on the bare hybridized modes to show that such long-range modulated order is unstable at all temperatures. We discuss the implications for the nearly ferroelectric SrTiO_{3} and KTaO_{3}, and we propose that these systems are melted versions of an underlying modulated state that is dominated by nonzero momentum thermal fluctuations except at the very lowest temperatures.
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