Silicon-Based Superslippery/Superhydrophilic Striped Surface for Highly Efficient Fog Harvesting

Fog-harvesting performance is influenced by surface wettability, patterned structure and the heat transfer coefficient. In this work, we have prepared different surfaces with a stripe array of superhydrophilic, superslippery and superslippery/superhydrophilic surfaces for fog harvesting on silicon substrates using photolithography and silver-assisted chemical etching. The surface wettability and heat transfer coefficients of the above samples have been investigated. We analyzed the contact angle, sliding angle and transport state of droplets on these surfaces. The fog-harvesting rate of all samples under different voltages of the cooling pad (V = 0, 2.0, 2.5, 3.0, 3.5 V) was measured. Results showed that the superslippery/superhydrophilic striped surface could achieve rapid droplet nucleation, directional transport and efficient collection due to its superhydrophilic striated channels and the Laplace pressure difference between different wettability regions. At a condensation voltage of 3.5 V, the fog-harvesting rate efficiencies of the uniformly striped superhydrophilic and superslippery surface were 1351 mg·cm^-2·h^-1 and 1265 mg·cm^-2·h^-1, respectively, while the fog-harvesting rate of the superslippery/superhydrophilic striped surface was 1748 mg·cm^-2·h^-1. Compared with the original silicon surface, the maximum fog-harvesting rate of the superslippery/superhydrophilic striped surface was improved by 86.9%. This study offers significant insights into the impact of heat transfer and silicon surface wettability on the process of fog collection.