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Cost-effective smartphone-based method for low range chemical oxygen demand analysis.

Inalmar D Barbosa Segundo1, Jussara C Cardozo1, Pollyana Souza Castro2

  • 1Renewable Energies and Environmental Sustainability Research Group, Institute of Chemistry, Federal University of Rio Grande do Norte, Campus Universitário, Av. Salgado Filho 3000, Lagoa Nova, Natal, RN CEP 59078-970, Brazil.

Methodsx
|August 14, 2023
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Summary

Researchers can now measure chemical oxygen demand (COD) using just a smartphone. This simple, low-cost method offers high accuracy for water quality monitoring, especially in developing nations.

Keywords:
CODDigital image colorimetryHSV image processingSmartphone-based method for low range chemical oxygen demand analysisSmartphone-based technology

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Area of Science:

  • Environmental Science
  • Analytical Chemistry
  • Water Quality Monitoring

Background:

  • Traditional chemical oxygen demand (COD) analysis often relies on expensive spectrophotometers, limiting accessibility in resource-constrained settings.
  • Decentralized environmental monitoring is crucial for effective water resource management and achieving global sustainability goals.

Purpose of the Study:

  • To develop and validate a simple, rapid, and cost-effective protocol for COD analysis using smartphone technology.
  • To provide a viable alternative to conventional spectrophotometric methods for researchers, particularly in developing countries.

Main Methods:

  • A protocol utilizing smartphone cameras and a free Android application analyzing HSV (hue, saturation, value) color parameters was developed.
  • Calibration was performed using theoretical potassium hydrogen phthalate values and digested COD samples.
  • The method's performance was evaluated based on coefficient of determination (R²), accuracy, and range.

Main Results:

  • The smartphone-based COD analysis achieved a coefficient of determination (R²) greater than 0.99, indicating high reliability.
  • The method demonstrated an average accuracy of 97% for samples within the 0 to 150 mg L⁻¹ COD range.
  • Smartphone analysis effectively substituted expensive spectrophotometers, showing high confidence levels.

Conclusions:

  • Smartphone-based COD measurement presents a promising, accessible tool for environmental analysis, particularly in decentralized monitoring scenarios.
  • This novel protocol supports Sustainable Development Goal 6 (Clean Water and Sanitation) by enhancing water quality assessment capabilities.
  • The method's efficiency in reading HSV values and its cost-effectiveness make it a valuable asset for laboratories and policy implementation.