Average-atom Ziman resistivity calculations in expanded metallic plasmas: Effect of mean ionization definition

We present calculations of electrical resistivity for expanded boron, aluminum, titanium, and copper plasmas using the Ziman formulation in the framework of the average-atom model. Our results are compared to experimental data, as well as to other theoretical calculations, relying on the Ziman and Kubo-Greenwood formulations, and based on average-atom models or quantum-molecular-dynamics simulations. The impact of the definition of ionization, paying particular attention to the consistency between the definition and the perfect free electron gas assumption made in the formalism, is discussed. We propose a definition of the mean ionization generalizing to expanded plasmas the idea initially put forward for dense plasmas, consisting in dropping the contribution of quasibound states from the ionization due to continuum ones. It is shown that our recommendation for the calculation of the quasibound density of states provides the best agreement with measurements.