Fabrication of 1D Ni nanochains@Zn²⁺ doping polypyrrole/reduced graphene oxide composites for high-performance...

Nowadays, electromagnetic radiation significantly impacts the normal operation of electronic devices and poses risks to human health. To effectively address this problem, the development of composites that exhibit exceptional electrochemical wave absorption through the combination of different components holds great promise. In this study, we have successfully prepared 1D Ni nanochains@Zn²⁺ doping polypyrrole/reduced graphene oxide (Ni NCs@Z-P/RGO, denoted as R-x) composites using a combination of hydrothermal, solvothermal, in situ polymerization, and physical blending methods. Notably, the R-2 composite demonstrates a remarkable minimum reflection loss (RL_min) of -63.58 dB at 14.3 GHz, with a thickness of 1.61 mm. Furthermore, the R-2 composite exhibits an impressive effective absorption bandwidth (EAB) of 5.08 GHz (11.92 GHz-17 GHz) at a thickness of 1.67 mm. These outstanding performances can be attributed to the synergistic effect of the different components and a well-thought-out structural design. Moreover, to showcase the practical applicability of the material, we have conducted additional investigations on the reduction of the radar cross-sectional area (RCS). The results strongly demonstrate that the prepared composite material, when used as a coating, effectively reduces the RCS value by up to 26.6 dB m² for R-2 at θ = 0°. The experimental methods and simulations presented in this study hold significant potential for application in wave absorption research and practical implementations. Additionally, the prepared Ni NCs@Z-P/RGO composites demonstrate feasibility as wave-absorbing materials for future utilization.